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Scientists have improved the efficiency of inexpensive solar cells – silicon will soon go down in history?

University of Washington Scientists Succeed in Improving Solar Cell Efficiency. Let’s make a reservation, we are not talking about the already familiar silicon batteries, which can be found, for example, in calculators, but about color-sensitized solar cells, which were discovered in 1991 by Michael Graetzel. They are photoelectrochemical cells that use photosensitized mesoporous oxide semiconductors.

Grätzel cell solar cells have many advantages: they are flexible, cheaper and easier to manufacture than silicon. Unfortunately, in terms of conversion efficiency, they are still significantly inferior to the latter.

To improve efficiency, it is necessary that the surface of the element absorbs light well. The material of which the Grätzel cell is composed has a homogeneous structure – all particles have the same size. On the one hand, you can increase the size of these particles, making them comparable to the wavelength of light – this will cause the light rays to be reflected many times inside the layer, increasing the proportion of light converted to electricity. On the other hand, the smaller the particles, the larger the total area of ​​their surface that captures light.

To resolve this contradiction, scientists proposed an interesting approach: to form microscopic balls from small granules (the top image shows a separate ball with a diameter of 300 nm, formed from 15 nm granules). The small size of the granules allows an increase in the surface area, and the relatively large size of the balls effectively traps the light rays, preventing them from being reflected from the surface. The second image shows a layer formed by millions of balls, and the lower one shows a light-absorbing surface with a thickness of about 10 microns, consisting of microscopic balls.

Believe it or not, the particles of one gram of material used in a solar cell have a total surface area of ​​about 100 square meters.m. According to the project participants, the result exceeded expectations.

In their development, scientists used zinc oxide. It is easier to work with, although it is less efficient than titanium oxide used in commercial batteries. The maximum efficiency previously achieved in zinc oxide batteries was 2.4%. The development made it possible to increase it by about 2.6 times, up to 6.2%. It is expected that the same effect can be obtained for titanium oxide, the batteries of which now have an efficiency of 11%. If successful, the performance of titanium oxide batteries will outperform silicon batteries. In this case, they will have to give way to new technology: cheaper and more efficient solar panels.

Source: University of Washington

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